Three - photon resonant four - photon ionization of H 2 via the C 1 ITu state

نویسندگان

  • V. McKoy
  • Arthur Amos Noyes
چکیده

Ab initio calculations are presented for the vibrational branching ratios in three-photon resonant fourphoton ionization of H2 via the C 1ITu state. Energy and internuclear distance dependences of the boundfree electronic transition .matrix element are explicitly included to estimate deviations from the FranckCondon approximation. While our calculated branching ratios confirm certain important trends seen experimentally, some differences remain.

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تاریخ انتشار 2012